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MATERIAL SAFETY DATA SHEET 1. Identification of the preparation/Supplier reference Trade Name: Liquid metals, lustres and essences CH6430 Bright Gold CH6431 Platinum CH6432 Mother of Pearl Chemical name: Organo metallic compound, resins and solvents Synonyms: None Supplier: Cromartie Hobbycraft Ltd Park Hall Road Longton Stoke-on-Trent ST3 5AY Emergency numbers 01782 319435 – email: enquiries@cromartie.co.uk 2. Composition Component CAS EINECS % of composition Refer to Table 1 3. Health Hazard Identification Inhalation; Will irritate the nose and upper respiratory tracts Ingestion: Will cause nausea and vomiting Eyes: Will sting and high concentrations will be irritating Skin: May cause redness and irritation, especially if spilled onto clothing and allowed to remain in contact with the skin over a period of time. 4. First Aid Measures Inhalation Remove patient to fresh air, loosen tight clothing and seek medical attention Ingestion Rinse mouth with water and give milk. Do not induce vomiting, seek medical advice Eyes Wash immediately with copious amounts of water or isotonic saline solution for 15 minutes. Seek medical advice Skin Remove contaminated clothing and wash skin with soap and water. Do not use solvents. Seek medical advice if symptoms persist. 5. Fire Fighting Measures Extinguishing Media: Carbon dioxide, dry powder or foam extinguishers Special Exposure hazard: The material is flammable and if ignited will burn producing toxic fumes. Personal protective equipment: Self contained breathing apparatus 6. Accidental Release Measures Leaks & Spills: Remove all sources of ignition. Small spills can be wiped up with absorbent paper. Cover larger spills with sand or other inert absorbent. Collect in a suitable container for disposal or further treatment. protection 7. Handling & Storage Handling: Use only under conditions of good local ventilation. Avoid contact with the skin and eyes. Do not eat, drink, smoke or apply cosmetics whilst using these materials Storage: Store in a sealed container in a cool dry place away from any sources of Ignition. 8. Exposure Control/Personal protective Equipment Engineering controls Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is normally recommended Personal protective equipment Where LEV is not practicable and exposure is likely to be excessive, approved respiratory protection to CEN standards prEN 140, 141, 143 or 149 should be worn. Protective gloves and overalls are recommended for prolonged contact. Vapour and fumes from drying, curing, firing or kilning operations should be discharged to the atmosphere in accordance with local and national regulations 9. Physical & Chemical properties Appearance & Odour Brown (except for P4384 and P4385, both colourless) varnish like liquid, with characteristic odour Flash point (ºC) Please refer to summary table Flammability Will ignite if heated or in contact with a flame Explosive properties Not explosive Oxidising properties Not oxidising Specific gravity 1-1.2 pH value Not applicable Melting point (ºC) No data available 10. Stability & Reactivity Chemical stability: The material is supplied in a stable condition but will lose solvent by evaporation. Note that the solvents are heavier than air and can accumulate, travel to sources of ignition and flashback. Conditions/materials to avoid: Avoid contact with strong oxidising agents such as chlorates, perchlorates, permanganates, nitric acid or sulphuric acid. Hazardous decomposition products: Cyclohexanone explodes when added to nitric acid and, on mixing with hydrogen peroxide it produces oily explosive peroxides Hazardous polymerization products: Not known 11. Toxicology Information Acute toxicology: There is no specific data available for this preparation data. Data for the components indicate that the oral toxicity LD50 (oral-rat) 200-2000mg/kg Health effects: The preparation is harmful and individual solvents are mild skin irritants and mild to severe eye irritants 12. Ecological information Ecotoxicity: The organic solvents are toxic to fish at a concentration of about 50ppm Persistence: The cured preparation, resins and plastics are only sparingly soluble in water and will pose no threat to the environment 13. Disposal Small spills can be absorbed onto paper and burnt in an incinerator, in accordance with local and national regulations. Large quantities can be mixed with sand and disposed of to landfill in accordance with local and national regulations. 14. Transport Information UN/SI No. 1236 UN Class 3 Packing group III Road UK Not classified ADR Not classified Sea IMO: For sea transport, these products are classified as a marine pollutant (P) contains O-dichlorobenzele Air ICAO: Not classified 15. Regulatory information EC Supply Labelling: Harmful - contains O-dichlorobenzene R-Phrases R10 - flammable R20/22 - harmful by inhalation and if swallowed R36/38 - irritating to eyes and skin R61 - may cause harm to the unborn child S-Phrases S20/21 - when using, do not eat, drink or smoke S24/25 - avoid contact with skin and eyes S26 - in case of contact with eyes, rinse immediately with plenty of water and seek medical advice S38 - in case of insufficient ventilation wear suitable respiratory equipment S51 - use only in well ventilated areas sure - obtain special instructions before use UK Occupational Refer to table 2 exposures limits*: * refer to HSE Guidance note EH40 In accordance with HSE Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitutes the user's assessment of workplace risk 16. Other information Summary per product: Refer to table 3 TABLE 1 COMPOSITIONProduct EINECS CASTurpentine 2323507 8006-64-2 O-dichlorobenzene 2024259 95-50-1 Cyclohexanol 2036306 108-93-0 Cyclohexanone 2036311 108-94-1 Methyl cyclohexanol 2471526 25639-42-3 di-iso-octylphthalate 2485235 27554-26-3 Camphor 2009450 76-22-2 White spirit 2324893 8052-41-3 Xyleone 2155357 1330-20-7 Tetrahydronaphthalene 2043402 119-64-2 Isophorone 2011260 78-59-1 Tetrahydrofurfuryl alcohol 2026256 97-99-4 TABLE 2 OCCUPATIONAL EXPOSURE LIMITS Product LTEL STELTurpentine 100ppm 150ppm PLEASE REFER O-dichlorobenzene - 50ppm TO SUMMARY Cyclohexanol 50ppm - TABLE FOR % in product Cyclohexanone 25ppm 100ppm Methyl cyclohexanol 50ppm 75ppm di-iso-octylphthalate 5mg/m3 - Camphor 2ppm 3ppm White spirit 100ppm 125ppm Xyleone 100ppm 150ppm Tetrahydronaphthalene None Isophorone - 5ppm Tetrahydrofurfuryl alcohol &nb
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